Third Matter / Exopoiesis

What if matter could sustain itself — without being alive?

An open research project exploring self-maintaining inorganic systems

Where it all began →

What is Third Matter?

Living things maintain themselves. Crystals are ordered but passive. What lies between?

We are designing a minimal chemical system — built from iron sulfide minerals — that maintains its own boundary, drives its own metabolism, and persists without being alive.

This is Third Matter: organized, self-sustaining, but not biological. A new category of material organization that could not arise naturally — engineered at the boundary between chemistry and life.

Key Results

6 iron sulfides, DFT proton barriers Vacancy-anchored S–H hopping from 43 meV (mackinawite) to 1.9 eV (greigite) — a ~40× range
R² ≈ 0.999 hop-distance scaling law Proton-transfer barrier predicted from jump geometry across the iron-sulfide family
MACE vs DFT foundation MLIP benchmark ML potentials (MACE, CHGNet) reproduce the kinetic trap qualitatively but disagree ~2.5× (ΔF‡ = 0.32–0.80 eV)
2 papers · open code & data Paper #1 submitted to Digital Discovery (RSC); Paper #2 in revision. Repositories public on GitHub
Lean 4 machine-checked theorems Core kinetic-model claims formally proven; an automated gate guards against AI hallucination
262,000 simulations Global sensitivity analysis (ORACLE), RF AUC = 0.982
G3c membrane architecture Pentlandite 200–500 nm + mackinawite 20–50 nm two-chamber stack

The Architecture

At the heart of Third Matter is the G3c membrane — a two-chamber system separated by a layered iron sulfide stack:

Acidic pH 2.5
Pentlandite 200–500 nm
Mackinawite 20–50 nm
Alkaline pH 8.5
⟵ e     H+ blocked     CO2 → HCOO
  • Pentlandite (outer layer): blocks protons (Ea = 1.43 eV), conducts electrons (σ = 10–100 S/cm)
  • Mackinawite (inner layer): catalyzes CO2 → formate at just 23 mV overpotential
  • The pH gradient (2.5 → 8.5) drives spontaneous electrochemistry — no external power needed

About

Igor Morozov — independent researcher, Ukraine.
 https://orcid.org/0009-0007-3863-1747

Graduated with distinction from Kharkiv National University of Radio Electronics (Computer Engineering; Electronics & Process Engineer, 1996). His working career then went into software engineering rather than the cleanroom — and years later it was AI that became the bridge back: a way to bring that semiconductor-era grounding in thin films and layered architectures, together with a programmer's toolkit, to the mineral membranes at the heart of this project. A first research project — citizen science at the frontier.

A semiconductor engineer's perspective on designing life-like matter.

This project is built entirely through human–AI collaboration using Claude (Anthropic). Every model, every literature review, every calculation — a partnership between human intuition and machine reasoning.

Collaborate

We are looking for collaborators:

Wet-lab partners

CV measurements of mackinawite, pentlandite thin-film synthesis, microfluidic prototyping

Computational collaborators

DFT surface calculations, molecular dynamics, CFD microfluidics simulation

Theorists

Chemical reaction network theory, non-equilibrium thermodynamics, autopoiesis formalism

If you work on iron sulfide electrochemistry, origin of life, or self-organizing systems — let's talk.

Get in touch